User Activity

They work using an ap. They work using wi-fi. If there is no wi-fi connection and I use my mobile data, will I be charged by O2/Virgin? Last year on holiday in Scotland, I used my mobile data to send photos to my friends, unaware that I'd be charged ...
I bought a new phone and contract yesterday, switching form Virgin. Do I have to dfo anything about the PAC code in oder to keep my Number. At the moment, my new phone is showing another number